A novel two-dimensional Mn(II) coordination polymer with 1,2-bis(imidazol-1-yl)ethane.
نویسندگان
چکیده
In the crystal structure of the title complex, poly[[diazidomanganese(II)]-di-1,2-bis(imidazol-1-yl)ethaneN:N 0 ], [Mn(N3)2(C8H10N4)2]n or [Mn(N3)2(bim)2]n, where bim is 1,2-bis(imidazol-1-yl)ethane, each Mn atom is six-coordinated in a distorted octahedral coordination environment to four N atoms from four bim ligands and two N atoms from two azide ligands. The Mn atoms, which lie on inversion centres, are bridged by four bim ligands to form a two-dimensional (4,4)-network. The azide ligands are monodentate (terminal).
منابع مشابه
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عنوان ژورنال:
- Acta crystallographica. Section C, Crystal structure communications
دوره 60 Pt 8 شماره
صفحات -
تاریخ انتشار 2004